Yup, what he said. I place the commercial octane booster products in a similar category to the bottled water or energy booster products. Wildly overpriced with little if any actual benefit, other than to the wallets of those selling the crap.
There is one scenario where higher octane might make your vehicle "perform" better. If your engine management system is retarding spark to adjust for low octane fuel and detonation, then yes, higher octane will reduce or eliminate that intervention by the engine management system and performance will be slightly better. The amount of "boost" that the commercial octane boosters provide, however, would be unlikely to make enough difference for anyone to actually "feel" the difference. It's not like going from 87 octane regular to 93 octane premium. Don't let the misleading names of the products fool you. 103+, 108, 110, or various other BS names do not equate to running those octane levels.
Buy the octane your manual calls for, and if the engine still pings then try a different brand or station. If it still pings, get the engine checked out for carbon deposits and then get it tuned to run correctly on the fuel available. Constantly wasting big bucks on so-called octane boosters is not something I'd be bragging about. There are a lot of people who convince themselves that the dubious products they buy are really doing what those ads claim. That doesn't prove that the products work, it just proves that people can fool themselves into seeing things that aren't really there. That is the power of modern advertising.
Jerry