Actually, putting bigger fulsac baffles in, would be moving more air through the motor. More air and same fuel is leaner. Leaner mixture is a hotter exhaust temp.
Traditionally when you put an high flow exhaust and high flow air cleaner on you richen the mixture and this helps lower temps.
Theses bikes come way lean from the factory to meet EPA rules.
Putting bigger baffles behind the cat ain't gonna change things all that much, except for the sound level.
Yeah, more air and same fuel would be leaner, but the larger baffles after the cat aren't going to be drawing any more air into the combustion chamber - at least nothing worth quibbling over. And the ECM will pick up on the fact (after the fact, but before the next one) that the mixture has changed and will put it right back as best it can. With only slip-on mufflers its job won't be too difficult. But mustn't forget that in this case we're talking about a can of worms that has a re-flashed ECM.
Changing out the complete exhaust and with a high-flow air cleaner, you probably would need to enrich the mixture - but not the same across the board. Who knows, might have an area or two where some needs taken away...
They're pretty lean, stock, but not dangerously so, and likely less than they'd need to be without the cat.
So long as the OP don't take it out of closed loop while throwing a bunch of fuel at it "to cool off the motor" there won't be any damaging heat off the cat.