I couldn't read through all of the comments... but according to my mechanic and my Chevy dealer (Silverado and Camaro), about the only 'Real' benefit is that the 99% Nitrogen filled tires do not cause the Tire Pressure Indicators to fail as often. Less oxygen... less condensation inside the tire... less corrosion to the TPI device.
I have not noticed any mpg gains. Other than the loss of pressure due to extreme temperature changes being more consistent... say -1psi per 10° below Cold Temp setting being established. While the Air filled tires were best guess, and when our temperatures hit -40°F and colder, the tires would develop flat spots due to the loss of pressure.
At some point you will find yourself needing to 'add' air if you ride in early Spring and Late Fall... or even in the Winter for some of you... and it's not likely that you'll have a Nitrogen fill station at your house, but keeping the tires at proper psi with the Nitrogen is more easily manageable.