I'm going to put a 2009 Fat cat on my 2011 SERGU, engine and AC are stock... I'll run a PC-V till I can afford a Thundermax.
I guess if you've already bought the PC-V it wouldn't hurt to use it, but I'd sell it if possible. You've already got a better ECM than the T-Max. I'd say your best money would be spent on a TTS kit with which to re-calibrate the ECM directly. By using a PC-V you'll be throwing away closed-loop and its adaptive fueling system in the stock ECM (which you've already paid for) and you'll most likely be dicking with the combustion monitoring through the spark-plug. The T-Max doesn't have that last part at all, and it doesn't use manifold pressure for either fueling or spark timing; MAP is far better at both of those, giving much finer control that's totally load-based.
But you won't be able to use the O2 sensors that fit that pipe with the stock ECM and you won't have sensor bungs of the proper configuration or size to use what came with your bike, so I wouldn't go that route either unless you want to (properly) install a couple of sensor bungs on the pipes.